01 - Preheat oven to 350°F. Line a 12-cup muffin tin with paper liners.
02 - In a mixing bowl, whisk together the flour, cocoa powder, sugar, baking soda, baking powder, and salt until evenly distributed.
03 - Add the buttermilk, vegetable oil, eggs, and vanilla extract to the dry mixture. Mix until just combined, then pour in the hot water and stir until the batter is smooth. The batter will be thin — this is normal.
04 - Divide the batter evenly among the prepared liners, filling each about two-thirds full.
05 - Bake for 18 to 20 minutes, or until a toothpick inserted into the center comes out clean. Transfer to a wire rack and cool completely.
06 - Beat the softened butter until light and creamy. Add the powdered sugar and beat for 1 minute. Mix in the marshmallow creme and vanilla extract, beating until the filling is fluffy. If the consistency is too thick, add milk one teaspoon at a time until reachable.
07 - Using a small knife or cupcake corer, remove a small portion from the center of each cooled cupcake, reserving the tops if desired. Transfer the cream filling to a piping bag and fill each cavity. Replace the reserved tops if using.
08 - Heat the heavy cream in a saucepan until steaming but not boiling. Pour over the chocolate chips and let sit for 2 minutes, then stir until smooth and glossy.
09 - Spoon or dip the tops of the cooled cupcakes into the ganache, coating evenly. Set aside until the glaze sets.
10 - Stir together the powdered sugar and milk until smooth and pipeable. Transfer to a piping bag fitted with a fine tip or a zip-top bag with a tiny corner snipped off. Pipe the classic swirl pattern across the top of each cupcake.
11 - Allow the ganache and icing to set before serving. Enjoy at room temperature for the best texture.